organic compounds
In the title compound, C9H18NO+·NO3-, the piperidinium ring adopts a slightly deformed chair conformation and the nitrate anion is disordered. The ions are arranged in hydrogen-bonded chains parallel to [001], in which the cations alternate with the anions. The intrachain hydrogen bonds are bifurcated and link the O atoms of the anions to the N atoms of the cations.
organic compounds
The title compound, C21H28O4, has a 4-acetoxy substituent positioned on the steroid face. The six-membered ring A assumes a conformation intermediate between 1,2-half chair and 1-sofa. A long Csp3-Csp3 bond is observed in ring B and reproduced in quantum-mechanical ab initio calculations of the isolated molecule using a molecular-orbital Hartree-Fock method. Cohesion of the crystal can be attributed to van der Waals interactions and weak C-HO hydrogen bonds.