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In the title compound, {[Na(H2O)4]2(C4H2N2O7)}n, the 1,5-dihydr­oxy-4,8,9-trioxa-2,6-diaza­bicyclo­[3.3.1]nona-2,6-diene-3,7-diolate anion lies across a twofold axis in the space group C2/c; there are two independent Na sites, one on a twofold axis and the other on a centre of inversion. Hydrogen bonds link the {[Na(H2O)4]+}n chains and diolate anions into a three-dimensional framework.
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