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The copper(II) ion in the synanti carboxyl­ate-bridged one-dimensional zigzag chain title complex, {[Cu(C16H18N3O2)]ClO4}n, exhibits a distorted trigonal–bipyramidal environment. Two N atoms and one carboxyl­ate O atom of the ligand form the basal plane, while the axial positions are filled by an N atom of the ligand and one O atom belonging to the carboxyl­ate group of an adjacent mol­ecule. The crystal packing is enhanced by C—H...O(perchlorate) hydrogen bonds.
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