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In the title hydrated mol­ecular salt, C5H7N2+·C7H3ClNO4·H2O, the ions and water mol­ecules assemble into ribbons of R65(22) rings along the c axis via O(water)—H...O, N+—H...O(water) and N—H...O hydrogen bonds. N—H...O hydrogen bonds connect adjacent ribbons along the c-axis direction via R44(12) rings, forming hydrogen-bonded layers. The CO2 and NO2 groups make dihedral angles of 81.8 (2) and 1.4 (2)°, respectively, with the ring in the anion.
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