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The new penta­hydrate of bis­(2,2′-bi­pyridine)­oxalatonickel(II) was obtained from a reaction at 281 K, whereas the previously reported tetra­hydrate was obtained at room temperature. The complex mol­ecules are involved in an extended system of hydrogen bonds with solvent water mol­ecules. Additionally, π–π inter­actions also contribute to the stabilization of the extended structure.
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