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The crystal structure of a mixed-valence iron phosphite has been solved from single-crystal X-ray diffraction data in the trigonal space group R\overline{3}m. The compound shows anionic [Fe3(HPO3)4]2- and [Fe(HPO3)2]- sheets stacked in a disordered manner along the c axis, with the K+ cations located in the inter­layer spaces.
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