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The crystal structures of three alkali tetra­germanates A2Ge4O9 (A = Na, K and Rb) are trigonal (space group P\overline{3}c1). The main building units are a three-membered ring of tetra­hedra, oriented within the (001) plane and forming tetra­hedral sheets. These sheets are connected to each other by two different regular isolated GeO6 octa­hedra via corner-sharing to build up a tetra­hedral-octa­hedral framework.
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