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The title compound, [Cu8(C15H10N3O3S)4Cl4(C3H7NO)2]·2C3H7NO, consisting of eight CuII cations, four trianionic 1-(2-oxidobenzoyl)-2-(2-oxo-2-phenyl­ethane­thioyl)hydrazine-1,2-diide ligands, four chloride ligands and two coordinated and two solvent di­methyl­formamide mol­ecules, crystallizes with the octa­nuclear mol­ecule located on an inversion centre. The two halves of the mol­ecule are connected by two bridging Cl atoms. This is the first example of an octa­nuclear complex based on a thio­semicarbazone-derived ligand.
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