metal-organic compounds
The title compound, [Fe{OS(CH3)2}6]Br3, is isostructural with [Fe{OS(CH3)2}6](NO3)3 [Tzou, Mullaney, Normand & Chang (1995), Acta Cryst. C51, 2249–2252]. The FeIII centre in the cation occupies a crystallographic site and has a distorted octahedral coordination, with an Fe—O distance of 2.000 (2) Å and O—Fe—O angles of 92.01 (7) and 87.99 (7)°.