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The cation of the title salt, C24H25N52+·2ClO4-, contains a tris­(2-pyridylmeth­yl)amine core in which one of the pyridine N atoms is protonated and a second pyridine N atom forms an additional C-N bond to another 2-pyridylmeth­yl group, resulting in a second pyridinium center. The protonated pyridinium hydrogen bonds to a pyridine ring of a neighboring dication. The hydrogen-bonded H atom is disordered between the two N atoms.
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