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The title compound, C7H7NO2S, forms centrosymmetric acid dimers which are connected through weak C—H...O interactions to form a tape. Adjacent tapes are arranged in a zigzag fashion with weak methyl–methyl interactions.

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The crystal structure of 4-nitro­phenyl­propiolic acid, C9H5NO4, is described. The carboxyl­ic acid functional group adopts the rare syn-anti conformation and the mol­ecules are arranged in a catemeric chain.
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