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In the title compound, [Re(C9H9N)(C14H12N2)(CO)3]PF6, the complex cation adopts a distorted octahedral geometry, with the Re atom at the center and a facial disposition of the three carbonyl ligands.

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The title compound, [CuCl2(C5H8N2)2], has been synthesized as part of a project aimed at the synthesis and characterization of scorpionate ligands with cyano substituents. The structure shows the Cu ion coordinated by two 3,5-dimethyl­pyrazole ligands and two chloride ligands in a tetrahedral coordination geometry.
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