organic compounds
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The title compound, C20H18N4, was obtained via the condensation of 4,5-dimethylbenzene-1,2-diamine with pyridine-2-carbaldehyde. The plane of the 2-(pyridin-2-yl) substitutent is canted by 2.75 (11)° from the plane of the benzimidazole system. The molecule exhibits an S(6) C—HN intramolecular hydrogen-bond motif. In the crystal, C—HN hydrogen bonds link pairs of molecules related by a crystallographic inversion center, forming R22(20) rings. Additional weak C—HN hydrogen bonds result in C(9) chains parallel to [001].