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In the crystal structure of the title compound, 4C5H6ClN2+·H2P6O184−, the [H2P6O18]4− anions are interconnected by O—H...O hydrogen bonds, leading to the formation of infinite ribbons extending along the a-axis direction. These ribbons are linked to the organic cations, via N—H...O and C—H...O hydrogen bonds, into a three-dimensional network. The six P atoms of the [H2P6O18]4− anion form a chair conformation. The complete cyclohexaphosphate anion is generated by inversion symmetry.
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