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The title compound, C10H9Cl2N3O3S, adopts a trans–cis conformation with respect to the position of chloropropionyl and chloronitrobenzene groups respectively, against the thiono about their C—N bonds. The conformation is stabilized by an intramolecular N—H
O hydrogen bond. In the crystal, there is a short ClCl contact with a distance of 3.386 (13) Å.
O hydrogen bond. In the crystal, there is a short ClCl contact with a distance of 3.386 (13) Å.organic compoundsOpen access
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In the title compound, C12H15FN2O2S, the molecule adopts a cis configuration of the fluorobenzoyl group with respect to the thiono group about their C—N bond. The dihedral angle between the fluorobenzoyl group and the thiourea N2CS fragment is 69.60 (11)°. An intramolecular N—HO hydrogen bond occurs. In the crystal, molecules form chains along the b-axis direction via O—HS and C—HO hydrogen bonds.
O hydrogen bond occurs. In the crystal, molecules form chains along the b-axis direction via O—HS and C—HO hydrogen bonds.organic compoundsOpen access
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The title compound, C13H18N2O2S, adopts a cis conformation between the methylbenzoyl and thiono groups across their thiourea C—N bond. However, the methylbenzoyl group and N2CS thiourea moiety are twisted by 15.03 (3)°. In the molecule there is an N—HO hydrogen bond. In the crystal, molecules are linked by O—HO interactions, generating chains extending along the c-axis direction.
O hydrogen bond. In the crystal, molecules are linked by O—HO interactions, generating chains extending along the c-axis direction.data reportsOpen access
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In the title compound, C15H11F2N3O2S, the dihedral angle between the fluorobenzene rings is 88.43 (10)° and that between the central semithiocarbazide grouping is 47.00 (11)°. The dihedral angle between the amide group and attached fluorobenzene ring is 50.52 (11)°; the equivalent angle between the carbonylthioamide group and its attached ring is 12.98 (10)°. The major twists in the molecule occur about the C—N—N—C bonds [torsion angle = −138.7 (2)°] and the Car—Car—C—N (ar = aromatic) bonds [−132.0 (2)°]. An intramolecular N—HO hydrogen bond occurs, which generates an S(6) ring. In the crystal, the molecules are linked by N—HO and N—HS hydrogen bonds, generating (001) sheets. Weak C—HO and C—HF interactions are also observed.
O hydrogen bond occurs, which generates an S(6) ring. In the crystal, the molecules are linked by N—HO and N—HS hydrogen bonds, generating (001) sheets. Weak C—HO and C—HF interactions are also observed.
