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In the crystal structure of the title compound, C17H12N2O2·2H2O, the carboxyl­ate group is linked via O—H...O hydrogen bonds to two water mol­ecules. The crystal packing is best described as parallel layers (viewed along the a axis) of viologen and water mol­ecules associated via O—H...O hydrogen bonds and π–π inter­actions, with a centroid–centroid separation of 3.8276 (9) Å.
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