Bis{μ-2-[bis­(pyridin-2-yl)methyl­idene]hydrazinecarbothio­amidato}bis­[bromido­copper(II)] methanol disolvate

In the centrosymmetric binuclear title compound, [Cu₂Br₂(C₁₂H₁₀N₅S)₂]·2CH₃OH, the Cu^II ion adopts a slightly dis­torted square-pyramidal coordination geometry. The hydrazine carbothio­amide moiety and one of the pyridyl rings together adopt an almost planar arrangement, with a maximum deviation of 0.052 (4) Å for the C atom of the thio­urea moiety. There are two mol­ecules of methanol solvent per complex in the asymmetric unit. The nonconventional intra­molecular C—H...Br hydrogen bonds make the mol­ecule more rigid, whereas the conventional N—H...N and O—H...Br inter­molecular hydrogen-bonding inter­actions, supported with N—H...π inter­actions, establish a supra­molecular linkage among the mol­ecules in the crystal. An intermolecular C—H...O inter­action is also present.