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In the title mol­ecule, C26H22P2Se2, both P atoms have distorted tetra­hedral environments, resulting in effective cone angles of 177 and 174°. Inversion twinning was detected and refined to a ratio of 0.35:0.65. Weak inter­molecular C—H...Se inter­actions are observed.

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In the title mol­ecule, C20H32NPSe, the P atom has a distorted tetra­hedral environment resulting in an effective cone angle of 172°. Weak inter­molecular C—H...Se inter­actions are observed.
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