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In 1,8-dibenzoyl-2,7-di­hydroxy­naphthalene, centrosymmetric dimeric aggregates arise from two intra- and inter­molecular O—H...O=C hydrogen bonds, forming head-to-tail square-shaped cyclic ...O...H...O...H... hydrogen bonds. These dimeric aggregates are connected into layers in the bc plane by inter­molecular (naphthalene)C—H...O=C inter­actions.
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