metal-organic compounds
The Cu atoms in the title complexes are five-coordinated in distorted trigonal bipyramidal environments by four N atoms of two 5,5′-dimethyl-2,2′-bipyridine ligands and one N atom of a dicyanamide anion, which is coordinated in a monodentate manner in the equatorial plane. The structures are stabilized by C—HN and C—HX hydrogen bonds (X = F and O) and π–π interactions between pyridine rings.