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The crystal packing of the title compound, C24H18Br2N2S2, is rationalized using the PIXEL method, which allows a separation of the inter­molecular inter­action energy into Coulombic, polarization, dispersion and repulsion contributions. Infinite (\overline{1}01) mol­ecular planes are formed through π–π stacking and other minor inter­actions, including a Br...S contact, with the σ hole of the Br atom pointing towards the S-atom lone pair. The title compound has crystallographically imposed twofold symmetry, with the twofold axis at the mid-point of the central C—C bond.

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In the title organic–inorganic hybrid material, the tetra­chlorido­zincate anions and 1-cyclo­hexyl­piperazine-1,4-diium dications are inter­connected via N—H...Cl and C—H...Cl hydrogen bonds to form layers parallel to the (001) plane. The cyclo­hexyl groups are located between these layers to form an infinite three-dimensional network.
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