metal-organic compounds
The title compound, [Zn2(C16H12O6)2(C12H8N2)2(H2O)2]n, consists of linear chains formed through 5-[4-(hydroxymethyl)benzyloxy]isophthalate (mabobdc) ligands linking five- and six-coordinated ZnII ions. The linear chains are linked into a bilayer network via O—HO hydrogen bonds. Adjacent bilayer structures are further linked with each other via C—HO hydrogen bonds and π–π and C—Hπ interactions to give a three-dimensional supramolecular framework. The results demonstrate the coordination and supramolecular chemistry of the mabobdc ligand.