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The title compound, [Zn2(C16H12O6)2(C12H8N2)2(H2O)2]n, consists of linear chains formed through 5-[4-(hydroxy­methyl)­benzyl­oxy]isophthalate (mabobdc) ligands linking five- and six-coordinated ZnII ions. The linear chains are linked into a bilayer network via O—H...O hydrogen bonds. Adjacent bilayer structures are further linked with each other via C—H...O hydrogen bonds and π–π and C—H...π inter­actions to give a three-dimensional supra­molecular framework. The results demonstrate the coordination and supra­molecular chemistry of the mabobdc ligand.
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