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The title compound, C16H12N2O8, exhibits two near-planar aromatic ester groups with ar­yl–ester dihedral angles of 2.1 (2) and 4.2 (3)°. The dihedral angle between the aromatic rings is 58.0 (1)°. The two nitro groups are tilted slightly from the plane of the aromatic rings, making dihedral angles of 14.1 (1) and 8.2 (2)°. In the crystal, mol­ecules are connected by weak C—H...O inter­actions, forming a three-dimensional network.

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The title compound, C16H13NO6, exhibits a biphenyl unit with a dihedral angle between the two aryl rings of 56.01 (5)°. The two ester groups vary slightly from planarity, with ar­yl–ester dihedral angles of 4.57 (5) and 16.73 (5)°. The nitro group is turned from the aromatic unit with an ar­yl–nitro dihedral angle of 48.66 (4)°. In the crystal, mol­ecules are connected by weak C—H...O inter­actions, forming a three-dimensional network.
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