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The title compound, lithium trimanganese bis­[tri­oxo­selenate(IV)] hexa­kis[hydrogentrioxoselenate(IV)], is built up from a vertex-sharing network of distorted MnIIIO6 octa­hedra, SeO3 and HSeO3 pyramids, and unusual Li(OH)6 octa­hedra, resulting in a dense three-dimensional structure. Mn, Li and one Se atom have site symmetries of \overline{1}, \overline{3}, and 3, respectively. An O—H...O hydrogen bond helps to establish the crystal packing.

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The title compound contains chains of edge-sharing distorted VO6 octa­hedra. Pyramidal TeO3 groups and unusual capped trigonal-bipyramidal LiO6 polyhedra complete a three-dimensional structure.
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