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In the title compound, [Fe2(CO)6(C7H7OS)2] or [Fe2(SPh-2-OMe)2(CO)6], each Fe atom is coordinated by three terminal carbonyl C atoms [Fe—C 1.779 (2)–1.819 (2) Å], two bridging S atoms [Fe—S 2.2747 (7)–2.2933 (7) Å] and the other Fe atom [Fe—Fe 2.4979 (5) Å], displaying a highly distorted octa­hedral geometry with cis angles ranging from 74.59 (3) to 105.88 (7)°.
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