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Two new diamagnetic FeII coordination compounds are ionic, with distorted octa­hedral [Fe(phen)3]2+ or [Fe(bpy)3]2+ complex cations (phen is 1,10-phenanthroline and bpy is 2,2′-bi­pyridine) and two uncoordinated planar tri­cyano­methanide (tcm) counter-anions balancing the positive charges of the cations. The structures are stabilized by π–π inter­actions between stacked aromatic rings of adjacent phen mol­ecules and by O—H...N hydrogen bonds.
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