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A three-dimensional polymeric potassium complex incorporating bridging water mol­ecules and 2,4-dicarb­oxy-5-sulfonato­benzoate ligands forms a one-dimensional inorganic chain with cage-like K4(SO3)2 repeat units. The chains are bridged by carb­oxy­lic acid groups to form a two-dimensional layer, and these layers are further linked by carboyxlate groups and benzene rings to generate a three-dimensional framework.
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