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The sterically hindered title complex, [Fe3Te2(C36H40N2)(CO)7], was obtained by substitution of two carbonyl groups in the [Fe33-Te)2(CO)9] cluster by the bulky redox-active N,N′-bis­(2,6-diisopropyl­phenyl)­acenaphthene-1,2-diimine (dpp-BIAN) ligand. The asymmetric unit contains two mol­ecules of the same geometry. The C=N bond lengths in dpp-BIAN indicate a rather low level of electron transfer from the cluster core to the dpp-BIAN ligand.
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