A one-dimensional silver(I) coordination polymer based on an asymmetric flexible N-donor carboxyl­ate ligand: catena-poly[(μ₃-4-{[(1-phenyl-1H-tetra­zol-5-yl)sulfanyl]­methyl}­benzo­ato-κ³O:O′:N⁴)silver(I)]

A one-dimensional silver(I) coordination polymer based on an asymmetric μ₃-bridging flexible carboxyl­ate ligand is reported. The structure displays intrachain π–π contacts and in addition forms a three-dimensional supramolecular framework. Thermogravimetric analysis and fluorescence spectroscopy reveal good thermal stability and a strong green luminescence at room temperature.