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In the mixed-ligand metal–organic title polymeric compound, [Zn(C10H8O4)(C10H16N6)]n or [Zn(PBEA)(BTH)]n [H2PBEA is benzene-1,4-diacetic acid and BTH is 1,6-bis­(1,2,4-triazol-1-yl)hexane], the asymmetric unit contains a ZnII atom, one half of a BTH ligand and one half of a doubly deprotonated H2PBEA ligand. Each ZnII centre lies on a crystallographic twofold rotation axis and is four-coordinated by two O atoms from two distinct PBEA2− ligands and two N atoms from two different BTH ligands in a {ZnO2N2} coordination environment. The three-dimensional topology of the title compound corresponds to that of a fivefold inter­penetrating diamond-like metal–organic framework.
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