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The title compound, C4H10N2O, crystallizes with two independent mol­ecules in the space group Cmc21. The first mol­ecule lies in a crystallographic mirror plane with x = 0, whereas the second mol­ecule lies on a general position with x1 \over 3. Each mol­ecule forms classical N—H...O=C hydrogen bonds, thereby leading to chains of mol­ecules parallel or anti­parallel, respectively, to the polar c axis.
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