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The crystal structure of bridged neoglycoside, 1-deoxy-1-[(methoxy)methylamino)]-2,5-di-O-triethylsilyl-β-D-glucofuranurono-γ-lactone revealed a 1T2-like conformation is preferred for the furanoid ring, while the γ-lactone system adopts an E4 conformation. This structure supports the properties associated with the anomeric effect for furanosides.
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