Download citation
Download citation

link to html
This work proposes the concept of a single chemistry which unifies the apparently contradictory bonding descriptions and structural models which are applied to molecular and extended solids, and thereby provides a more rational understanding of these materials.

Download citation
Download citation

link to html
The extended Zintl–Klemm concept accounts for the structures of the three dimeric cyclotrisilicate anions [Si6O17]10−, [Si6O16]8− and [Si6O15]6− as Zintl polyanions of composition [Ψ-S4P2]10−, [Ψ-S2P4]8– and [Ψ-P6]6−, respectively.
Follow Acta Cryst. B
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds