research papers
This work proposes the concept of a single chemistry which unifies the apparently contradictory bonding descriptions and structural models which are applied to molecular and extended solids, and thereby provides a more rational understanding of these materials.
research papers
The extended Zintl–Klemm concept accounts for the structures of the three dimeric cyclotrisilicate anions [Si6O17]10−, [Si6O16]8− and [Si6O15]6− as Zintl polyanions of composition [Ψ-S4P2]10−, [Ψ-S2P4]8– and [Ψ-P6]6−, respectively.