Unique thermodynamic relationships for Δ_fH^o and Δ_fG^o for crystalline inorganic salts. I. Predicting the possible existence and synthesis of Na₂SO₂ and Na₂SeO₂

Á. Vegas, J. F. Liebman and H. D. B. Jenkins

Unique thermodynamic relationships for Na₂SO_x and Na₂S₂O_x salts, and prediction of the thermodynamic stability of Na₂SO₂ and Na₂SeO₂ and the connection with the oxidation–pressure concept are discussed.

Keywords: volume-based thermodynamics (VBT); oxidation–pressure concept; condensed phases; structural science.

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Unique thermodynamic relationships for ΔfHo and ΔfGo for crystalline inorganic salts. I. Predicting the possible existence and synthesis of Na2SO2 and Na2SeO2

Unique thermodynamic relationships for Δ_fH^o and Δ_fG^o for crystalline inorganic salts. I. Predicting the possible existence and synthesis of Na₂SO₂ and Na₂SeO₂