Download citation
Download citation

link to html
A charge-assisted hydrogen-bonding network involving N—H...O and O—H...O hydrogen bonds stabilizes the crystal of the title salt, C5H8N3+·H2PO4. The dihydrogen phosphate anions form one-dimensional chains along [100], via O—H...O hydrogen bonds. The 2-amino-4-methyl­pyrimidinium cations are linked to these chains by means of two different kinds of N—H...O hydrogen bonds. Neighbouring chains are linked via C—H...N and C—H...O hydrogen bonds forming two-dimensional slab-like networks lying parallel to (01-1).

Download citation
Download citation

link to html
The title compound, C17H20N4O2, was prepared by the reaction between 1,3-di­amino­propane and isatoic anhydride in water. The carbonyl O atoms are involved in intra­molecular hydrogen bonding with the amine group and inter­molecular hydrogen bonding with an amide H atom of an adjacent mol­ecule. In the crystal, pairs of N—H...O hydrogen bonds link mol­ecules into inversion dimers and further N—H...O hydrogen bonds link the dimers into ladder-like chains along the a axis.
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds