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In the title complex, {[Zn(NCS)2(C15H15N9)2]·H2O}n, the ZnII ion is located on an inversion centre and is six-coordinated in a distorted octa­hedral geometry, coordinated by N atoms from four bridging 1,3,5-tris­(1,2,4-triazol-1-ylmeth­yl)benzene (ttmb) ligands and two terminal SCN counter-anions. Two of the three triazol groups in each ttmb ligand link the ZnII atoms, forming a looped-chain structure along [0-11]. The lattice water molecule shows half-occupancy due to disorder around an inversion centre.

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In the title mol­ecule, C16H19BrO3, all non-H atoms apart from the Br atom are approximately coplanar, with a maximum deviation of 0.242 (4) Å. The C-C-C-Br torsion angle is 66.5 (4)°.
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