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In the title compound, [Ni(C9H7O2)(C16H36N4)]ClO4·H2O, the macrocyclic 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane ligand (L) folds around the NiII atom, which is also chelated by the carboxyl­ate group. The geometry is a distorted N4O2 octa­hedron. In the crystal, adjacent mol­ecules are connected by O—H...O and N—H...O hydrogen bonds into a zigzag chain parallel to [010].
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