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The asymmetric unit of the title compound, {[Zn(C16H16O4Si)(C12H10N4)]·H2O}n, consists of one ZnII ion, two half 3,3′-(dimethyl­silanedi­yl)dibenzoate ligands and two half 1,1′-(1,4-phenyl­ene)di-1H-imidazole ligands. The ZnII ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two ZnII ions are bridged by two carboxyl­ate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent mol­ecules are hydrogen bonded within the chain along the c axis.
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