organic compounds
Open access
In the title compound, C13H9Cl2NO, the meta-Cl atom in the benzoyl ring is positioned anti to the C=O bond, while the ortho-Cl atom in the aniline ring is positioned syn to the N—H bond. The two aromatic rings are almost coplanar, making a dihedral angle of 4.73 (5)°. The crystal structure is stabilized by N—HO hydrogen bonds, which link the molecules into chains along the b axis.
organic compounds
Open access
The title compound, C10H7ClN2O5·H2O, crystallizes with a half-molecule each of N-(2-chloro-4-nitrophenyl)maleamic acid (located on a mirror plane) and water (located on a twofold rotation axis) in the asymmetric unit. The main molecule is planar by symmetry and its conformation is stabilized by an intramolecular O—HO hydrogen bond. In the crystal, N—HO and O—HO hydrogen bonds link the molecules into a three-dimensional network.
organic compounds
Open access
In the title compound, C15H14ClNO, the ortho- and meta-methyl substituents in the aniline ring are anti to the N—H bond. The dihedral angle between the benzoyl and aniline benzene rings is 95.0 (1)°. N—HO hydrogen bonds and C—Hπ interactions link the molecules in the crystal structure.