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The title compound, (C15H25N2O)[FeCl4], consists of one matrinium cation {matrine is (7aS,13aR,13bR,13cS)-dodeca­hydro-1H,5H,8H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]-naphthyridin-10-one} and one [FeCl4] anion. One ring of the matrinium cation has a half-chair conformation, whereas the others have chair conformations. Chiral chains of the title compound are formed by C—H...O and N—H...O hydrogen bonds.

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In the title compound, [CuCl2(C5H4ClN)2(H2O)], the CuII atom is coordinated by one water mol­ecule, two Cl ions and two 2-chloro­pyridine mol­ecules. The structure is built up via O—H...Cl hydrogen bonds and stablized by π–π stacking and Cl...Cl inter­actions.
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