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The principal molecule of the title mol­ecule, C12H8ClN3O3·C3H7NO, is essentially planar. The two benzene rings make a dihedral angle of only 6.9 (1)°. The nitro group is slightly twisted with respect to the benzene ring to which it is attached [3.7 (1)°]. The dimethyl­formamide solvent mol­ecule and the azobenzene mol­ecule are linked through a strong O—H...O hydrogen bond. In the crystal structure, the mol­ecules are stacked through π–π inter­actions along [010]. Some weak C—H...O inter­actions stabilize the packing.
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