organic compounds
The principal molecule of the title molecule, C12H8ClN3O3·C3H7NO, is essentially planar. The two benzene rings make a dihedral angle of only 6.9 (1)°. The nitro group is slightly twisted with respect to the benzene ring to which it is attached [3.7 (1)°]. The dimethylformamide solvent molecule and the azobenzene molecule are linked through a strong O—HO hydrogen bond. In the crystal structure, the molecules are stacked through π–π interactions along [010]. Some weak C—HO interactions stabilize the packing.