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The structure of the title compound, (C8H12N)[TlBr4], is characterized by tetracoordinate thallium, forming a regular tetrahedron TlBr4 with Tl-Br distances ranging between 2.528 (2) and 2.562 (2) Å. Chains of TlBr4 tetrahedra oriented along the c axis form pseudo-hexagonal rings, containing two columns formed by obliquely stacked amine cations.
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