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The title compound, also known as sodium nicotinate, Na+·C6H4NO2-, consists of two unique Na atoms coordinated to two unique pyridine-3-­carboxyl­ate ligands through the N atoms and carboxylate groups. One Na atom and one pyridine-3-­carboxyl­ate ligand lie on a twofold axis. Extensive Na coordination results in a three-dimensional array comprising infinite NaO2CR chains linked by intrachain Na-N bonds.
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