Analysis of N—H...O hydrogen bonds in new C(O)—NH—P(O)-based phosphoric triamides and analogous structures deposited in the Cambridge Structural Database

Four new structures belonging to the phosphoric triamide family have been studied, and their N—H...O hydrogen bonding is compared with that in 118 analogous structures from the Cambridge Structural Database.

Hirshfeld surface analysis of new phosphoramidates

New phosphoric triamide structures having different segments [C(=O)NH]P(=O)[N]₂, [O]₂P(=O)[N] and [N]₂P(=O)OP(=O)[N]₂ have been analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots, providing a detailed description of salient features in the crystal structures.