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The bond lengths and angles in the title compound, C40H24N4O2S, are normal. The dihedral angles between the dibenzothio­phene-S,S-dioxide and two quinoxaline groups are 34.88 (1) and 45.86 (1)°.

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In the mol­ecule of the title compound, C40H24N4S, the two benzene rings fused to the thio­phene ring form a dihedral angle of 2.3 (2)°. In the crystal structure, there are no significant hydrogen-bonding inter­actions, but there are π–π stacking inter­actions between mol­ecules.
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