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In the title complex, [Cu(C4H4O5)(C10H8N2)(H2O)], the chiral L-malate group, which acts as a tridentate ligand, the bidentate 2,2′-bipyridine ligand and the water mol­ecule provide an octa­hedral coordination of the CuII atom with strong Jahn–Teller distortion. Inter­molecular O—H...O hydrogen bonds stabilize the crystal packing.

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In the title compound, C14H12O4, the two ester groups are twisted away from the attached rings by 43.9 (2) and 41.8 (2)°. The crystal packing is stabilized by C—H...O hydrogen bonds.

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The title complex, C4H16N33+·H3O+·2C10H6O6S22−·3.5H2O, comprises one diethyl­enetriammonium trication, one oxonium cation, two naphthalene-1,6-disulfonate dianions and three-and-a-half water mol­ecules. The oxonium cation donates a proton to each of three acceptors, forming strong hydrogen bonds, O—H...O [2.476 (4), 2.473 (4) and 2.503 (4) Å]. O—H...O and N—H...O hydrogen bonds link the title complex into layers parallel to the (010) plane.
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