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The title PtIV complex, [PtCl4(C16H28N4O6)] or trans-[PtCl4{NH=C(Et)ON=C(Me)C(=O)OEt}2], possesses a crystallographically imposed centre of symmetry. The coordination environment of the metal centre is a slightly distorted octa­hedron. An intra­molecular N—H...N hydrogen bond between the imine H atom and the oxime N atom stabilizes the E configuration of the imine groups.

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The title compound, [Pt(C3H3N2)Cl3(C3H4N2)2], has mirror symmetry. The PtIV atom has a slightly distorted octa­hedral geometry, with three facial Cl atoms and three N atoms, the latter from one pyrazolate (pz) and two pyrazole (pzH) ligands. There is an intra­molecular N—H...N...H—N hydrogen-bonding system, with N...N distances of 2.747 (7) Å.
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