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The title PtIV complex, [PtCl4(C16H28N4O6)] or trans-[PtCl4{NH=C(Et)ON=C(Me)C(=O)OEt}2], possesses a crystallographically imposed centre of symmetry. The coordination environment of the metal centre is a slightly distorted octa­hedron. An intra­molecular N—H...N hydrogen bond between the imine H atom and the oxime N atom stabilizes the E configuration of the imine groups.
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