organic compounds
In the title compound, C19H21BrN2O2S, the fused pyrrolidine rings adopt envelope conformations. The molecular packing is stabilized by weak intermolecular C—HO interactions and van der Waals forces.
organic compounds
In the crystal structure of the title compound {systematic name: 4-(6-fluoro-1,2-benzisoxazol-3-yl)-1-hydroxy-1-[2-(2-methyl-4-oxo-3,4,6,7,8,9-hexahydro-2H-pyrido[1,2-a]pyrimidin-3-yl)ethyl]piperidine N-oxide hydrogen peroxide methanol solvate}, C23H27FN4O3·H2O2·CH3OH, the asymmetric unit contains one molecule of risperidone N-oxide, one methanol solvent molecule and one hydrogen peroxide molecule. The piperidine ring adopts a chair conformation, while the tetrahydropyridine ring has a sofa conformation. The hydrogen peroxide molecule links the risperidone molecules to form a chain. O—HO and C—HO interactions stabilize the crystal packing.
organic compounds
The crystal structure of the title compound, C17H21N4S+·C6H4NO2−, [systematic name: 1-methyl-4-(2-methyl-10H-thieno[2,3-b][1,5]benzodiazepin-4-yl)hexahydropyrazin-1-ium nicotinate] is reported. The central seven-membered heterocycle is in a boat conformation, while the piperazine ring displays a chair conformation with its methyl group oriented equatorially. The coulombic interaction between olanzapinium and nicotinate ions is supplemented by intra- and intermolecular N—HO hydrogen bonds, forming infinite chains along the c axis.