metal-organic compounds
In the title compound, [Ru(C4H3N2S)2(C18H15P)2]·CHCl3, the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiolate ligands and two P atoms from the triphenylphosphine ligands. Intramolecular π–π interactions between the pyrimidine and phenyl rings of triphenylphosphine are observed.
metal-organic compounds
The new mononuclear copper(II) complex, [CuCl(C10H8N2)2]BF4·CH2Cl2, was prepared by a new procedure using photo-irradiation and a nitrogen atmosphere. X-ray analysis reveals a slightly distorted trigonal–bipyramidal coordination geometry of copper(II); the axial ligands and the CuII atom deviate slightly from linearity [N—Cu—N = 175.3 (3)°].